Real-time atomistic observation of structural phase transformations in individual hafnia nanorods.
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| Abstract |    :  
                  High-temperature phases of hafnium dioxide have exceptionally high dielectric constants and large bandgaps, but quenching them to room temperature remains a challenge. Scaling the bulk form to nanocrystals, while successful in stabilizing the tetragonal phase of isomorphous ZrO, has produced nanorods with a twinned version of the room temperature monoclinic phase in HfO. Here we use in situ heating in a scanning transmission electron microscope to observe the transformation of an HfO nanorod from monoclinic to tetragonal, with a transformation temperature suppressed by over 1000°C from bulk. When the nanorod is annealed, we observe with atomic-scale resolution the transformation from twinned-monoclinic to tetragonal, starting at a twin boundary and propagating via coherent transformation dislocation; the nanorod is reduced to hafnium on cooling. Unlike the bulk displacive transition, nanoscale size-confinement enables us to manipulate the transformation mechanism, and we observe discrete nucleation events and sigmoidal nucleation and growth kinetics.  | 
        
| Year of Publication |    :  
                  2017 
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| Journal |    :  
                  Nature communications 
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| Volume |    :  
                  8 
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| Number of Pages |    :  
                  15316 
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| Date Published |    :  
                  2017 
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| URL |    :  
                  https://doi.org/10.1038/ncomms15316 
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| DOI |    :  
                  10.1038/ncomms15316 
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| Short Title |    :  
                  Nat Commun 
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